Masoud Nabavizadeh, Mehrangiz Bahrami, Mohammad Reza Halvagar, Elvira De Giglio, Mario Latronico, Piero Mastrorilli. Heteroatom (N, O, and S)-Based Biomolecule-Functionalized Graphene Oxide: A Bifunctional Electrocatalyst for Enhancing Hydrazine Oxidation and Oxygen Reduction Reactions. Electrocatalytic Oxidation of Alcohol with Cobalt Triphosphine Complexes. Speelman, Sharon Hammes-Schiffer, Aaron M. Journal of the American Chemical Society 2021, 143 Selective Chloride-Mediated Neat Ethanol Oxidation to 1,1-Diethoxyethane via an Electrochemically Generated Ethyl Hypochlorite Intermediate. Advanced Spatiotemporal Voltammetric Techniques for Kinetic Analysis and Active Site Determination in the Electrochemical Reduction of CO2. Role of High-Spin Species and Pendant Amines in Electrocatalytic Alcohol Oxidation by a Nickel Phosphine Complex. Thilina Gunasekara, Yicheng Tong, Amy L.Enhanced Hydrazine Oxidation on Histidine-Functionalized Graphene-Based Electrocatalysts. Electrochemical Conversion of Alcohols into Acidic Commodities on Nickel Sulfide Nanoparticles. Junshan Li, Xi Tian, Xiang Wang, Ting Zhang, Maria Chiara Spadaro, Jordi Arbiol, Luming Li, Yong Zuo, Andreu Cabot.ACS Applied Materials & Interfaces 2022, 14 Heterostructured Ru/Ni(OH)2 Nanomaterials as Multifunctional Electrocatalysts for Selective Reforming of Ethanol. Weidong Ao, Changgen Cheng, Huijun Ren, Zhishuai Fan, Peiqun Yin, Qing Qin, Zhe-Ning Chen, Lei Dai.
Polyoxometalates-Functionalized Electrodes for (Photo)Electrocatalytic Applications: Recent Advances and Prospects. Bruno Fabre, Clément Falaise, Emmanuel Cadot.This article is cited by 62 publications. The results suggest that 1 is one of the most active molecular electrocatalysts for methanol and ethanol oxidation. The numbers of aldehyde and acid products per catalyst were also calculated and compared with the literature reported values. The total faradaic efficiencies of electrocatalytic oxidation of both alcohols exceed 94%. These results demonstrate that electrocatalytic oxidation of ethanol and methanol occurs via two- and four-electron oxidation processes to yield aldehydes and acids. Similarly, the oxidation of methanol generates formaldehyde and formic acid which then condense with methanol to form dimethoxymethane and methyl formate, respectively. The products detected by NMR, gas chromatography (GC), and GC-mass spectrometry from oxidation of ethanol are 1,1-diethoxyethane and ethyl acetate formed from condensation of acetaldehyde or acetic acid with excess ethanol. To identify the oxidation products, preparative scale bulk electrolysis experiments were undertaken. Under these conditions, the initial form of 1 also exhibits considerable reactivity, especially in neutral solution containing 1.0 M NaNO 3. Voltammetric studies with dissolved and surface-confined forms of 10– suggest that the oxidized forms of 1 can act as active catalysts for alcohol oxidation in both aqueous (over a wide pH range covering acidic, neutral, and alkaline) and alcohol media. Highly efficient electrocatalytic oxidation of ethanol and methanol has been achieved using the ruthenium-containing polyoxometalate molecular catalyst, 10– ( 10–).
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